I typically avoid that scenario altogether and just leave it curly when the weather's against me, but on the rare occasion I do straighten I use Argan oil and hairspray. Finding a lightweight hairspray is key-I used one by Pantene at one point but I don't know if they make it anymore and I don't know of any other drugstore brands. If you're up for spending some serious cash, Alterna makes a brushable hair spray; Sebastian's Shaper hairspray is also supposed to be brushable, as is Lamaur Vita-E (though I'm not so sure that I'd ever use that, the only time I've ever seen that is when my older relatives had it, and that was a long time ago...)