Nope.
Skills count too much to be able to say if a person is wearing low or high end makeup.
On the other hand, we shouldn't forget that high end doesn't necessarily mean quality (like Chanel's eyeshadows? Jesus, everytime I swatch them they just look so sheer and cheap!! You just need to go to a L'Oreal counter and there you go, same identical eyeshadow for much less money)
However, I might guess sometimes if a product worn by a person is low or high end by the finish of it. Last time I was looking at my colleague's lipgloss and wondering what it was, it was so shiny, too shiny to be a low end lipgloss. I ended up asking her and it was MAC.